Cobalt (II) nitrate (Co(NO3)2) exists as a hydrate with the composition of 37.1% water and 62.9% cobalt nitrate by mass. Determine the molecular formula for this hydrate.

Respuesta :

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Answer:

Co(NO₃)₂·6H₂O

Explanation:

Assume that you have 100 g of the hydrate.

Then you have 62.9 g Co(NO₃)₂ and 37.1 g H₂O.

1. You will need a chemical equation with masses and molar masses, so let’s gather all the information in one place.

[tex]M_{r}[/tex]:                                           182.94      18.02

                 Co(NO₃)₂·xH₂O ⟶ Co(NO₃)₂ + xH₂O

Mass/g:                                         62.9          37.1

2. Use the molar masses of each compound to calculate its number of moles.

[tex]\text{Moles of Co(NO}_{3})_{2} = \text{62.9 g} \times \frac{\text{1 mol} }{\text{182.94 g}} = \text{0.3438 mol}[/tex]

[tex]\text{Moles of H}_{2}\text{O} = \text{37.1 g} \times \frac{\text{1 mol} }{\text{18.02 g}} = \text{ 2.059 mol}[/tex]

3. Calculate the molar ratio of the two products.

Divide each number by the smaller number of moles (0.3438 mol).

[tex]\text{Moles of Co(NO}_{3})_{2}:\text{Moles of H}_{2}\text{O} = \frac{\text{0.3438 mol}}{\text{0.3438 mol}}:\frac{\text{2.059 mol}}{\text{0.3438 mol}} = 1: 5.988[/tex]

4. Round off each number to the closest integer.

[tex]\text{Moles of Co(NO}_{3})_{2}:\text{Moles of H}_{2}\text{O} \approx 1:6[/tex]

1 mol of Co(NO₃)₂ combines with 6 mol H₂O, so x = 6.

The formula of the hydrate is Co(NO₃)₂·6H₂O.