Answer:
[tex]\boxed{\text{110.4 g of CaCl$_{2 }$ and 234.5 g of water}}[/tex]
Explanation:
1. Mass of CaCl₂
[tex]\text{Let m = mass of CaCl}_{2}\\\\\begin{array}{rcl}\text{Mass percent} & = & \dfrac{\text{Mass of CaCl}_{2}}{\text{Total mass}} \times 100 \%\\\\32.0 \% & = & \dfrac{m}{\text{344.9 g}} \times 100 \% \\\\\text{32.0 $\times$ 344.9 g} & = & 100 m\\\\m & = &\dfrac{\text{32.0 $\times$ 344.9 g}}{100}\\\\ & = &\textbf{110.4 g}\\\end{array}\\\text{You need $\boxed{\textbf{110.4 g}}$ of calcium chloride}[/tex]
2. Mass of water
[tex]\text{Let m = mass of water}\\\begin{array}{rcl}\\\text{Mass of water + mass of CaCl}_{2} & = & \text{Mass of solution}\\m + 110.4 & = & 344.9\\m & = &\mathbf{234.5}\\\end{array}\\\text{The mass of water needed is $\boxed{\textbf{234.5 g}}$}[/tex]