At 40.8C the value of Kw is 2.92 3 10214. a. Calculate the [H1] and [OH2] in pure water at 40.8C. b. What is the pH of pure water at 40.8C? c. If the hydroxide ion concentration in a solution is 0.10 M, what is the pH at 40.8C?

Respuesta :

Answer :

(a) The concentration of hydrogen ion and hydroxide ion are, [tex]1.708\times 10^{-7}M[/tex].

(b) The pH of pure water is, 6.78

(c) The pH of solution is, 13

Explanation :

(a) First we have to calculate the concentration of hydrogen ion and hydroxide ion.

As we know that,

[tex]K_w=[H^+][OH^-][/tex]

In pure water, the concentration of hydrogen ion and hydroxide ion are equal. So, let the concentration of hydroxide ion and hydrogen ion be, 'x'.

[tex]2.92\times 10^{-14}=(x)\times (x)[/tex]

[tex]2.92\times 10^{-14}=(x)^2[/tex]

[tex]x=1.708\times 10^{-7}M[/tex]

The concentration of hydrogen ion and hydroxide ion are, [tex]1.708\times 10^{-7}M[/tex].

(b) Now we have to calculate the pH of pure water.

[tex]pH=-\log [H^+][/tex]

[tex]pH=-\log (1.708\times 10^{-7})[/tex]

[tex]pH=6.78[/tex]

The pH of pure water is, 6.78

(c) In this, first we have to calculate the pOH when the concentration of hydroxide ion is, 0.10 M.

[tex]pOH=-\log [OH^-][/tex]

[tex]pOH=-\log (0.10)[/tex]

[tex]pOH=1[/tex]

Now we have to calculate the pH.

[tex]pH+pOH=14\\\\pH=14-pOH\\\\pH=14-1=13[/tex]

The pH of solution is, 13