The enthalpy of combustion of benzoic acid (C6H5COOH) which is often used to calibrate calorimeters, is −3227 kJ/mol. When 1.09 g of benzoic acid was burned in a calorimeter, the temperature increased by 3.662◦C. What is the overall heat capacity of the calorimeter? The overall heat capacity includes the calorimeter hardware and the water that is in it. Answer in units of kJ/ ◦C.

Respuesta :

Answer : The heat capacity of the bomb calorimeter [tex]7.865kJ/^oC[/tex]

Explanation :

First we have to calculate the heat released by the combustion.

[tex]q=n\times \Delta H[/tex]

where,

q = heat released by combustion = ?

n = moles of benzoic acid = [tex]\frac{\text{Mass of benzoic acid}}{\text{Molar mass of benzoic acid}}=\frac{1.09g}{122.122g/mole}=0.00893mole[/tex]

[tex]\Delta H[/tex] = enthalpy of combustion = 3227 kJ/mole

Now put all the given values in the above formula, get:

[tex]q=(0.00893mole)\times (3227kJ/mole)=28.8kJ[/tex]

Now we have to calculate the heat capacity of the bomb calorimeter.

Heat released by the reaction = Heat absorbed by the calorimeter

[tex]q=c\times \Delta T[/tex]

where,

q = heat released by the reaction  = 28.8 kJ = 28800 J

[tex]c[/tex] = heat capacity of calorimeter = ?

[tex]\Delta T[/tex] = change in temperature = [tex]3.662^oC[/tex]

Now put all the given values in the above formula, we get:

[tex]28800J=(c\times 3.662^oC)[/tex]

[tex]c=7864.55J/^oC=7.865kJ/^oC[/tex]

Therefore, the heat capacity of the bomb calorimeter [tex]7.865kJ/^oC[/tex]