Explanation:
Given,
The heat of combustion of octane = 1.308×10³ kcal/mol
It means that combustion of 1 mole of octane produces 1.308×10³ kcal of energy
Given mass = 406 g
Molar mass of octane = 114.23 g/mol
The formula for the calculation of moles is shown below:
[tex]moles = \frac{Mass\ taken}{Molar\ mass}[/tex]
Thus,
[tex]Moles= \frac{406\ g}{114.23\ g/mol}[/tex]
Moles of octane = 3.5542 moles
Combustion of 3.5542 moles produces 3.5542×1.308×10³ kcal of energy
Energy released from 406 grams of octane = 4.649×10³ kcal
Also given,
The heat of combustion of ethanol = 326.7 kcal/mol
It means that combustion of 1 mole of octane produces 326.7 kcal of energy
Given mass = 406 g
Molar mass of octane = 46.07 g/mol
The formula for the calculation of moles is shown below:
[tex]moles = \frac{Mass\ taken}{Molar\ mass}[/tex]
Thus,
[tex]Moles= \frac{406\ g}{46.07\ g/mol}[/tex]
Moles of octane = 8.8127 moles
Combustion of 8.8127 moles produces 8.8127×326.7 kcal of energy
Energy released from 406 grams of ethanol= 2879.11 kcal = 2.879×10³ kcal
It is less.