One milligram of a compound of molecular weight 160 is dissolved in 10 mL of ethanol, and the solution is poured into a 1-cm UV cell. The UV spectrum is taken, and there is an absorption at ????max = 247 nm. The maximum absorbance at 247 nm is 0.50. Calculate the value of ???? for this absorption.

Respuesta :

Answer:

The value of molar absorptivity of the compound is [tex]800 L mol^{-1} cm^{-1}[/tex].

Explanation:

Using Beer-Lambert's law :

[tex]A=\epsilon \times C\times l[/tex]

A = absorbance of solution

C = concentration of solution = [tex]2.00\times 10^{-3}M[/tex]

l = path length = 1.00 cm

[tex]\epsilon[/tex] = molar absorptivity coefficient

[tex]Concentration (C)= \frac{\text{moles of compound}}{\text{Volume of the solution(L)}}[/tex]

Moles of compound = [tex]\frac{1 mg}{160 g/mol}=\frac{0.001 g}{160 g/mol}=6.25\times 10^{-6} mol[/tex]

Volume of the solution = 10 mL = 0.010 L

[tex]C=\frac{6.25\times 10^{-6} mol}{0.010 L}=0.000625 mol/L[/tex]

A = 0.50 , l = 1 cm

[tex]0.50=\epsilon \times 0.000625 mol/L\times 1 cm[/tex]

[tex]\epsilon =\frac{0.50}{0.000625 mol/L\times 1 cm}=800 L mol^{-1} cm^{-1}[/tex]

The value of molar absorptivity of the compound is [tex]800 L mol^{-1} cm^{-1}[/tex].