A sample of He gas (2.0 mmol) effused through a pinhole in 53 s. The same amount of an unknown gas, under the same conditions, effused through the pinhole in 248 s. The molecular mass of the unknown gas is __________ g/mol.

Respuesta :

Answer:

Molecular mass of unknown gas is 87.58 grams per mol.

Explanation:

Let x be the molecular mass of the unknown gas.

Rate of effusion of a gas and its molecular mass is related as:

r ∝ [tex]\frac{1}{\sqrt{M} }[/tex]

where r is rate and M is molecular mass.

Molecular mass of He gas = 4 g/mol

Given: Same amount of gas is effused and at same conditions.

Let us say V mL of gas effused.

Then rate = V/t where t is time taken for effusion.

[tex]t_{He}=53\ s\\t_{unknown\ gas}=248\ s[/tex]

[tex]r=\frac{V}{t}=\frac{k}{\sqrt{M} }[/tex]

Since same amount of gases are effused V doesn't matter.

We can say:

t ∝ √M ⇒

then

[tex]\frac{53}{248}=\frac{\sqrt{4} }{\sqrt{x} }\\x=87.58\ g\ per\ mol[/tex]

Hence molecular mass of unknown gas is 87.58 grams per mol.