The fluorocarbon compound C2Cl3F3 has a normal boiling point of 47.6 °C. The specific heats of C2Cl3F3(l) and C2Cl3F3(g) are 0.91 J/g.K and 0.67 J/g.K, respectively. The heat of vaporization for the compound is 27.49 kJ/mol.
Calculate the heat required to convert 75.0 g of C2Cl3F3 from a liquid at 11.50 °C to a gas at 80.30 °C.

Respuesta :

Answer:

The heat required to convert 75.0 g of [tex]C_2Cl_3F_3[/tex] from a liquid at 11.50 °C to a gas at 80.30 °C is 15.103 kiloJoules.

Explanation:

1) Heat required to raise the temperature of fluorocarbon compound from 11.50°C to 47.6 °C= [tex]Q_1[/tex]

[tex]C_2Cl_3F_3(l,284.65 K)\rightarrow C_2Cl_3F_3(l,320.75 K)[/tex]

Mass of fluorocarbon compound = m = 75.0 g

Specific heat of fluorocarbon compound ,c= 0.91 J/gK

Change in temperature = [tex]\Delta T=320.75 K-284.65 K=36.1 K[/tex]

[tex]Q_1=m\times c\times \Delta T[/tex]

[tex]=75.0 g\times 0.91 J/g K\times 36.1 K=2,463.82 J[/tex]

2) Heat required to raise the change the state of of fluorocarbon compound from liquid to gas= [tex]Q_2[/tex]

[tex]C_2Cl_3F_3(l)\rightarrow C_2Cl_3F_3(g)[/tex]

Mass of fluorocarbon compound = m = 75.0 g

Moles of fluorocarbon compound = [tex]\frac{75.0 g}{187.5 g/mol}=0.4 mol[/tex]

The heat of vaporization for the compound = [tex]\Delta H_{vap}=27.49 kJ/mol[/tex]

[tex]Q_2= \Delta H_{vap}\times 0.4 mol=27.49 kJ/mol\times 0.4 mol=10.996 kJ[/tex]

[tex]Q_2=10.996 kJ = 10,996 J[/tex] (1 kJ= 1000 J)

3) Heat required to raise the temperature of fluorocarbon compound from 47.6 °C to 80.30°C= [tex]Q_3[/tex]

[tex]C_2Cl_3F_3(g,320.75 K)\rightarrow C_2Cl_3F_3(g,353.45 K)[/tex]

Mass of fluorocarbon compound = m = 75.0 g

Specific heat of fluorocarbon compound ,c'= 0.67 J/gK

Change in temperature = [tex]\Delta T'=353.45 K-320.75 K=32.7 K[/tex]

[tex]Q_3=m\times c'\times \Delta T'[/tex]

[tex]=75.0 g\times 0.67 J/g K\times 32.7 K=1,643.18 J[/tex]

The heat required to convert 75.0 g of [tex]C_2Cl_3F_3[/tex] from a liquid at 11.50 °C to a gas at 80.30 °C:

[tex]Q_1+Q_2+Q_3=2,463.82 J+10,996 J+1,643.18 J=15,103 J= 15.103 kJ[/tex]

The heat required to convert 75.0 g of C2Cl3F3 from a liquid at 11.50 °C to gas at 80.30 °C is mathematically given as

Q = 7916.59 J

What is the heat required to convert 75.0 g of C2Cl3F3 from a liquid at 11.50 °C to gas at 80.30 °C?

Question Parameter(s):

has a normal boiling point of 47.6 °C.

The specific heats of C2Cl3F3(l) and C2Cl3F3(g) are 0.91 J/g.K and 0.67 J/g.K, respectively

The heat of vaporization for the compound is 27.49 kJ/mol.

Generally, the equation for the Total Heat  is mathematically given as

Q = Q1+ Q2+ Q3

Therefore

Q1 = m * cL * dTL

Q2 = m * Lv

Q3= m * cG * dTG

Where latent heat of vaporization is given as

Lv / M = 27.49 kJ/mol / 187.5 gr/mol

Lv / M =0.1466 kJ/g

Hence

Q1 = 38 g * 0.91 * ( 47.6°C - 12.3°C)

Q1= 1186.09 J

Q2= 38 g * 0.1466 kJ/g * 1000J/kJ

Q2= 5570.8 J

Q3= 38 g * 0.67 J/gK * (93.15°C - 47.6°C )

Q3=  1159.70 J

In conclusion,

Q =1186.09 J + 5570.8 J + 1159.70 J

Q = 7916.59 J

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