Ar is a solid below -189 oC with a face-centered cubic array of atoms and a supposed density of 1.32 g/cm3. Assuming that the atoms are spheres in contact along the face diagonal, what is the radius of a Ar atom (in Angstroms)? An angstrom = 10-10 m or 10-8 cm. Hint, first find the length of an edge of the unit cell. (Argon's actual density is 1.65 g/cm3.)

Respuesta :

Answer:

The radius the Argon atom in [tex]2.072\ \AA [/tex]

Solution:

As per the question:

Density of the solid, [tex]\rho = 1.32\ g/cm^{3}[/tex]

No. of atoms present in FCC lattice, Z = 4

Now,

Mass of Argon, m = 40 g/mol

Density of the unit cell is given by the formula:

[tex]\rho = \frac{m\times Z}{N_{o}\times a^{3}}[/tex]                      (1)

where

a = edge length

[tex]N_{o}[/tex] = Avogadro's number

Now,

[tex]a^{3} = \frac{40\times 4}{6.022\times 10^{23}\times 1.32} = 2.012\times 10^{- 22}[/tex]

[tex]a = (2.012\times 10^{- 22})^{\frac{1}{3}} = 5.86\times 10^{- 8}\ cm[/tex]

Now,

In FCC unit cell, the relation between the radius, R and the edge length, a is given by:

[tex]R = \frac{a}{2\sqrt{2}}[/tex]

[tex]R = \frac{5.86\times 10^{- 8}}{2\sqrt{2}} = 2.07\times 10^{- 8}\ cm = 2.072\ \AA [/tex]