Consider the following generic reaction for which Kp = 5.51 × 105 at 25°C:

2R(g)+A(g)⇌2Z(g)

What is the value of Kc for the reaction at the same temperature?

1.37 × 10^9
2.25 × 10^4
1.35 × 10^7
5.51 × 10^5

Respuesta :

Answer:

[tex]K_c=1.35\times 10^7[/tex]

Explanation:

The relation between Kp and Kc is given below:

[tex]K_p= K_c\times (RT)^{\Delta n}[/tex]

Where,  

Kp is the pressure equilibrium constant

Kc is the molar equilibrium constant

R is gas constant

T is the temperature in Kelvins

Δn = (No. of moles of gaseous products)-(No. of moles of gaseous reactants)

For the first equilibrium reaction:

[tex]2R_{(g)}+A_{(g)}\rightleftharpoons2Z_{(g)} [/tex]

Given: Kp = [tex]5.51\times 10^5[/tex]  

Temperature =  25°C

The conversion of T( °C) to T(K) is shown below:

T(K) = T( °C) + 273.15  

T = (25 + 273.15) K = 298.15 K  

R = 0.082057 L atm.mol⁻¹K⁻¹

Δn = (2)-(2+1) = -1  

Thus, Kc is:

[tex]5.51\times 10^5= K_c\times (0.082057\times 299)^{-1}[/tex]

[tex]K_c\frac{1}{24.535043}=551000[/tex]

[tex]K_c=13518808.69=1.35\times 10^7[/tex]