contestada

Magnesium metal burns in air to form a mixture of magnesium oxide (MgO, M = 40.31) and magnesium nitride (Mg3N2, M = 100.95). A 1.000 g sample of magnesium ribbon is burned in air to give 1.584 g of the oxide/nitride mixture. What percentage of the magnesium is present in the form of the nitride?

Respuesta :

Answer:

26.95 %

Explanation:

Air contains the highest percentage of oxygen and nitrogen gases. Magnesium then combines with both of the gases:

[tex]2 Mg (s) + O_2 (g)\rightarrow 2 MgO (s)[/tex]

[tex]3 Mg (s) + N_2 (g)\rightarrow Mg_3N_2 (s)[/tex]

Firstly, find the total number of moles of magnesium metal:

[tex]n_{Mg} = \frac{1.000 g}{24.305 g/mol} = 0.041144 mol[/tex]

Let's say that x mol react in the first reaction and y mol react in the second reaction. This means:

[tex]x + y = 0.041144 mol[/tex]

According to stoichiometry, we form:

[tex]n_{MgO} = x mol, n_{Mg_3N_2} = \frac{y}{3} mol[/tex]

Multiplying moles by the molar mass of each substance will yield mass. This means we form a total of:

[tex]m_{MgO} = 40.31x g, m_{Mg_3N_2} = \frac{y}{3} 100.95 g = [/tex]

The total mass is given, so we have our second equation to solve:

[tex]40.31x + 33.65y = 1.584[/tex]

We have two unknowns and two equations, we may then solve:

[tex]x + y = 0.041144[/tex]

[tex]40.31x + 33.65y = 1.584[/tex]

Express y from the first equation:

[tex]y = 0.041144 - x[/tex]

Substitute into the second equation:

[tex]40.31x + 33.65(0.04144 - x) = 1.584[/tex]

[tex]40.31x + 1.39446 - 33.65x = 1.584[/tex]

[tex]6.66x = 0.18954[/tex]

[tex]x = 0.028459[/tex]

[tex]y = 0.041144 - x = 0.012685[/tex]

Moles of nitride formed:

[tex]n_{Mg_3N_2} = \frac{y}{3} = 0.0042282 mol[/tex]

Convert this to mass:

[tex]m_{Mg_3N_2} = 0.0042282 mol\cdot 100.95 g/mol = 0.4268 g[/tex]

Find the percentage:

[tex]\omega_{Mg_3N_2} = \frac{0.4268 g}{1.584 g}\cdot 100\% = 26.95 \%[/tex]