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If an aqueous solution of lead(II) nitrate (Pb(NO3)2) is mixed with an aqueous solution of potassium chloride (KCl) the precipitate is:

Respuesta :

Answer: lead(II) chloride PbCl2

Explanation:

Pb(NO3)2 + 2KCl —> PbCl2 + 2KNO3

Taking into account the definition of net ionic equation, a precipitate of PbCl₂ is formed when an aqueous solution of lead(II) nitrate (Pb(NO₃)₂) is mixed with an aqueous solution of potassium chloride (KCl) .

The net ionic equation is a chemical equation for a reaction that lists only the species that participate in the reaction.

In other words, an ionic equation is a chemical equation where electrolytes in aqueous solution are written as dissociated ions.  

In this case, the balanced equation will be:

Pb(NO₃)₂ (aq) + 2 HCl (aq) → PbCl₂ (s) + 2 HNO₃ (aq)

where (aq) means aqueous and (s) solid.

Taking into account that:

  • All Cl⁻, Br⁻ and I⁻ salts are soluble.
  • All salts of NO₃⁻, C₂H₃O₂⁻, ClO₃⁻ and ClO₄⁻ are soluble.
  • All Ag⁺, Pb²⁺ and Hg₂²⁺ salts are insoluble.

The total ionic equation in separated aqueous solution will be:

Pb²⁺(aq) + 2 NO₃⁻(aq) + 2 H⁺ (aq) + 2 Cl⁻ (aq) → PbCl₂ (s) + 2 H⁺ (aq) + 2 NO₃⁻ (aq)

A spectator ion is an ion that appears both as a reactant and as a product in an ionic equation.

Spectator ions can be either cations (positively charged ions) or anions (negatively charged ions).

When writing a net ionic equation, spectator ions found in the original equation are ignored. Thus, the total ionic reaction is different from the net chemical reaction.

In this case, H⁺ and NO₃⁻ are the spectator ions because they appear unchanged in both the product and the reagent. So these ions cancel out by writing the net ionic equation and you get:

Pb²⁺(aq) + 2 Cl⁻ (aq) → PbCl₂ (s)

Since PbCl₂ is an insoluble salt, it will precipitate.

Finally, a precipitate of PbCl₂ is formed when an aqueous solution of lead(II) nitrate (Pb(NO₃)₂) is mixed with an aqueous solution of potassium chloride (KCl) .

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