Respuesta :
Answer:
Therefore the mass of an atom of this metal is 55.74 g/mol.
Explanation:
Given, edge length = 2.866 [tex]\AA[/tex]
=2.866×10⁻¹⁰ m.
Density of the metal = 7.87 g/ cm³
Body centered cubic has 2 atom per unit cell.
Atomic mass: Atomic mass is mass of the component per atom.
Density: Density is the ratio of mass to volume.
[tex]Density=\frac{mass}{volume}[/tex]
mass = number of atom × atomic mass = Z×M
Volume =( edge length)³× Avogadro Number = [tex]a^3\times N_A[/tex]
z= number of atom =2
M=atomic mass=?
a=edge length=2.866×10⁻¹⁰ m=[tex]=2.866\times 10^{-10} \times 10^2 cm[/tex]
[tex]N_A[/tex] =Avogadro Number =6.023×10²³
[tex]Desity(d)=\frac{Z\times M}{a^3\times N_A}[/tex]
[tex]\Rightarrow M=\frac{d \times a^3\times N_A}{Z}[/tex]
[tex]\Rightarrow M=\frac{7.87 g/cm^3 \times( 2.866\times 10^{-10} \times 10^2 cm)^3 \times 6.023\times 10^{23}/mol}{2}[/tex]
[tex]\Rightarrow M = 557.94\times 10^{-30}\times 10^{29}[/tex] g/mol
⇒M = 55.74 g/mol
Therefore the mass of an atom of this metal is 55.74 g/mol.
The mass of an atom of this metal is 9.26 × 10⁻²³ grams
Given that:
- the edge length (a) of the unit cell = 2.366 Å
- the density of the metal = 7.87 g/cm³
The density [tex]\rho[/tex] of a unit cell can be computed as:
[tex]\mathbf{Density (\rho) = \dfrac{Mass \ of \ the \ unit \ cell }{volume \ of \ the \ unit \ cell }}[/tex]
where;
- [tex]\mathbf{ mass\ of \ unit\ cell (m) = \dfrac{effective \ no. \ of \ an \ atom (Z) \times \ Molar \ mass (M) }{avogadro's \ No (N_o)}}[/tex]
- Volume of the unit cell = a³
∴
[tex]\mathbf{ density \ of \ unit\ cell (m) = \dfrac{effective \ no. \ of \ an \ atom (Z) \times \ Molar \ mass (M) }{avogadro's \ No (N_o)\times a^3}}[/tex]
Making the molar mass (M) the subject, we have:
[tex]\mathbf{ Molar \ mass (M) = \dfrac{ avogadro's \ No (N_o)\times a^3 \times \rho}{effective \ no. \ of \ an \ atom (Z) }}[/tex]
where;
- a = 2.866 Å
- a = 2.866× 10⁻¹⁰ m
- a = (2.866 × 10⁻¹⁰) × 10¹² pm = 286.6 pm
- a = (286.6 pm × 10⁻¹⁰ cm)/1 pm = 2.866 × 10⁻⁸ cm
Now, the molar mass (M) can be estimated as:
[tex]\mathbf{ Molar \ mass (M) = \dfrac{6.023 \times 10^{23} mol^{-1} \times (2.866 \times 10^{-8} \ cm )^3 \times 7.87 g/cm^3}{2}}[/tex]
[tex]\mathbf{ Molar \ mass (M) = \dfrac{111.5876557}{2}\ g/mol}[/tex]
[tex]\mathbf{ Molar \ mass (M) =55.79 \ g/mol}[/tex]
Finally, the mass of an atom of this metal is:
[tex]\mathbf{mass (m) = \dfrac{55.79 g/mol}{ 6.023 \times 10^{23} \ mol^{-1}}}[/tex]
mass (m) of an atom of this metal = 9.26 × 10⁻²³ grams
Learn more about body-centered cubic structure here:
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