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Because of the toxicity of mercury compounds, mercury(I) chloride is used in antibacterial salves. The mercury(I) ion Hg22+ consists of two bound Hg+ ions. How many grams of mercury(I) chloride are needed to saturate 4900 km3 of water (the volume of Lake Michigan)? (Ksp = 1.5 × 10−18).

Respuesta :

Answer:

[tex] 1.668\times 10^{12} [/tex] grams of mercury(I) chloride are needed to saturate [tex]4900 km^3[/tex] of water .

Explanation:

[tex]Hg_2Cl_2\rightleftharpoons Hg_2^{2+}+2Cl^-[/tex]

                   S       2S

Solubility product of mercury (I) chloride= [tex]K_{sp}=1.5\times 10^{-18}[/tex]

The expression of solubility product is given as:

[tex]K_{sp}=[Hg_2^{2+}][Cl^-]^2[/tex]

[tex]K_{sp}=[S][2S]^2=4S^2[/tex]

[tex]1.5\times 10^{-18}=4S^3[/tex]

[tex]S= 7.211\times 10^{-7} M[/tex]

Volume of water  V = [tex]4900 km^3[/tex]

[tex]km^3=10^{12} L[/tex]

[tex]V=4900\times 10^{12} L[/tex]

Moles of mercury(I) chloride in solution= n

[tex]n=S\times V=7.211\times 10^{-7} M\times 4900\times 10^{12} L[/tex]

Mass of n moles of mercury(I) chloride: m

[tex]=7.211\times 10^{-7} M\times 4900\times 10^{12} L\times 472 g/mol[/tex]

[tex]m= 1.668\times 10^{12} g[/tex]

[tex] 1.668\times 10^{12} [/tex] grams of mercury(I) chloride are needed to saturate [tex]4900 km^3[/tex] of water .