Consider the following reaction 2 N2O(g) → 2 N2(g) + O2(g) rate = k [N2O] . For an initial concentration of N2O of 0.50 M, calculate the concentration of N2O remaining after 2.0 min if k = 3.4 × 10−3 s −1 . 1. 0.17 M 2. 0.50 M 3. 0.55 M 4. 0.33 M 5. 0.66 M

Respuesta :

Answer: 0.33 M

Explanation:

As the order of the reaction is one, Expression for rate law for first order kinetics is given by:

[tex]t=\frac{2.303}{k}\log\frac{a}{a-x}[/tex]

where,

k = rate constant  = [tex]3.4\times 10^{-3}\text{s}^{-1}[/tex]

t = age of sample  = 2.0 min = [tex]2.0\times 60s=120s[/tex]

a = let initial amount of the reactant  = 0.50 M

a - x = amount left after decay process  = ?

Now put all the given values in above equation, we get

[tex]120=\frac{2.303}{3.4\times 10^{-3}}\log\frac{0.50}{(a-x)}[/tex]

[tex]\log\frac{0.50}{(a-x)}=0.18[/tex]

[tex]\frac{0.50}{(a-x)}=1.5[/tex]

[tex]{(a-x)}=0.33M[/tex]

Thus the concentration of [tex]N_2O[/tex] remaining after 2.0 min is 0.33 M