The conversion of cyclopropane to propene occurs with a first-order rate constant of . How long will it take for the concentration of cyclopropane to decrease from an initial concentration 0.080 mol/L to 0.053 mol/L?

Respuesta :

This is an incomplete question, here is a complete question.

The conversion of cyclopropane to propene occurs with a first-order rate constant of 2.42 × 10⁻² hr⁻¹. How long will it take for the concentration of cyclopropane to decrease from an initial concentration 0.080 mol/L to 0.053 mol/L?

Answer : The time taken will be, 17.0 hr

Explanation :

Expression for rate law for first order kinetics is given by:

[tex]t=\frac{2.303}{k}\log\frac{a}{a-x}[/tex]

where,

k = rate constant  = [tex]2.42\times 10^{-2}\text{ hr}^{-1}[/tex]

t = time passed by the sample  = ?

a = initial concentration of the reactant  = 0.080 M

a - x = concentration left = 0.053 M

Now put all the given values in above equation, we get

[tex]t=\frac{2.303}{2.42\times 10^{-2}}\log\frac{0.080}{0.053}[/tex]

[tex]t=17.0\text{ hr}[/tex]

Therefore, the time taken will be, 17.0 hr