Ferris & Mona used the ORP sensor to titrate a ferrous ammonium sulfate solution, (NH4)2Fe(SO4)2 with KMnO4 titrant. They titrated a 12.50 mL aliquot of the Fe+2 solution with 0.0215 M MnO4- solution and determined that the equivalence point was at 10.8 mL. What is the molarity of the Fe+2 solution?

Respuesta :

Answer:

Molarity of [tex]Fe^{2+}[/tex] solution is 0.0928 M.

Explanation:

Balanced equation: [tex]5Fe^{2+}+MnO_{4}^{-}+8H^{+}\rightarrow 5Fe^{3+}+Mn^{2+}+4H_{2}O[/tex]

Number of moles of [tex]MnO_{4}^{-}[/tex] in 10.8 mL of 0.0215 M [tex]MnO_{4}^{-}[/tex] solution

= [tex]\frac{0.0215}{1000}\times 10.8moles[/tex] = 0.000232 moles

Let's assume molarity of  [tex]Fe^{2+}[/tex] solution is S(M)

Number of moles of [tex]Fe^{2+}[/tex] in 12.50 mL of S(M) [tex]Fe^{2+}[/tex] solution

= [tex]\frac{S}{1000}\times 12.50moles[/tex] = 0.0125S moles

According to balanced equation, 5 moles of  [tex]Fe^{2+}[/tex] react with 1 mol of [tex]MnO_{4}^{-}[/tex]

So, 0.0125S moles of [tex]Fe^{2+}[/tex] react with [tex]\frac{0.0125S}{5}[/tex] moles of [tex]MnO_{4}^{-}[/tex]

Hence, [tex]\frac{0.0125S}{5}=0.000232[/tex]

         or, S = 0.0928

So, molarity of [tex]Fe^{2+}[/tex] solution is 0.0928 M.