This question is incomplete because it is not specified which balls should be measured and compared. However, it is possible to give indications on "how to measure and compare two balls"
You can measure and compare the sizes of two balls using a measuring tape or observation.
To measure a ball, you need to know the circumference's distance. To do this, you have to take a measuring tape and measure the circunference's distance and then compare that of both balls to determine which is the largest.
On the other hand, another method that can be used is observation, this method is recommended when the difference is visibly evident.
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