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Consider the single‑step, bimolecular reaction. CH3Br+NaOH⟶CH3OH+NaBr When the concentrations of CH3Br and NaOH are both 0.120 M, the rate of the reaction is 0.0080 M/s. What is the rate of the reaction if the concentration of CH3Br is doubled? rate: M/s What is the rate of the reaction if the concentration of NaOH is halved? rate: M/s What is the rate of the reaction if the concentrations of CH3Br and NaOH are both increased by a factor of 5? rate: M/s

Respuesta :

Answer:

Explanation:

CH₃Br+NaOH⟶CH₃OH+NaBr

It is a single step bimolecular reaction so  order of reaction is 2 , one for CH₃Br and one for NaOH .

rate of reaction = k x [CH₃Br] [ NaOH]

.008 = k x .12 x .12

k = .55555

when concentration of CH₃Br is doubled

rate of reaction = .555555 x [.24] [ .12 ]

= .016 M/s

when concentration of NaOH  is halved

rate of reaction = .555555 x [.12] [ .06 ]

= .004  M/s

when concentration of both CH₃Br and Na OH is made 5 times

rate of reaction = .555555 x .6 x .6

= 0.2 M/s

if the concentration of the CH3Br in the reaction is doubled; then the rate of the reaction is also doubled and it becomes 0.016 M/s. If the concentration of NaOH is being halved, the rate of reaction also gets halved. If both concentrations for CH3Br and NaOH are increased by a factor of 5, the rate of reaction will increase by 25 times.

The single-step, bimolecular reaction given shows the chemical combination between two different molecular substances in the given reaction.

CH₃Br + NaOH ⟶ CH₃OH + NaBr

The rate of the reaction (r) = K[CH₃Br][NaOH].

where;

[tex]\mathbf{rate = -\dfrac{ d[CH_3Br ] }{dt} = -\dfrac{ d[NaOH] }{dt} }[/tex]

From the given information; if the concentration of the CH3Br in the reaction is doubled;

   

[tex]\mathbf{rate = -\dfrac{1}{2}\dfrac{d[CH_3Br]}{dt}}[/tex]

[tex]\mathbf{2 \times rate = -\dfrac{d[CH_3Br]}{dt}}[/tex]

[tex]\mathbf{2 \times 0.008 \ M/s = -\dfrac{d[CH_3Br]}{dt}}[/tex]

[tex]\mathbf{ -\dfrac{d[CH_3Br]}{dt} =0.016 \ M/s }[/tex]

If the concentration of NaOH is being halved, then, we have:

[tex]\mathbf{rate = -\dfrac{d[NaOH]}{dt}}[/tex]

[tex]\mathbf{rate = -2 \times \dfrac{d[NaOH]}{dt}}[/tex]

[tex]\mathbf{\dfrac{rate}{2} = - \times \dfrac{d[NaOH]}{dt}}[/tex]

where;

  • rate = 0.0080 M/s

[tex]\mathbf{\dfrac{0.0080 \ m/s}{2} = - \dfrac{d[NaOH]}{dt}}[/tex]

[tex]\mathbf{- \dfrac{d[NaOH]}{dt} = 0.004 \ M/s}[/tex]

If both concentrations for CH3Br and NaOH are increased by a factor of 5, then:

[tex]\mathbf{rate = - \dfrac{1}{5}\dfrac{d[CH_3Br]}{dt} = -\dfrac{1}{5} \dfrac{d[NaOH]}{dt}}[/tex]

[tex]\mathbf{5 \times 5 \times rate = -\dfrac{d[CH_3Br]}{dt} = -\dfrac{d[NaOH]}{dt} }[/tex]

[tex]\mathbf{5 \times 5 \times 0.0080 \ M/s = -\dfrac{d[CH_3Br]}{dt} = -\dfrac{d[NaOH]}{dt} }[/tex]

[tex]\mathbf{0.2 \ M/s = -\dfrac{d[CH_3Br]}{dt} = -\dfrac{d[NaOH]}{dt} }[/tex]

Thus, the rate of the reaction is increased by 25 times faster.

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