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Pb2+(aq) + 2 e- --> Pb(s) Eo = -0.13V Zn2+(aq) + 2 e- --> Zn(s) Eo = -0.76V 9. Given the half-cell potentials above, when the reaction Zn(s) + Pb2+(aq) --> Zn2+(aq) + Pb(s) is made into a voltaic cell, the Ecell is: A. 0.63 V B. -0.63 V C. 0.89 D. 0.89

Respuesta :

Answer: The [tex]E_{cell}[/tex] is 0.63 V

Explanation:

In the given reaction :

[tex]Zn(s)+Pb^{2+}(aq)\rightarrow Zn^{2+}(aq)+Pb(s)[/tex]

Here Zn undergoes oxidation by loss of electrons, thus act as anode. Lead undergoes reduction by gain of electrons and thus act as cathode.

[tex]E^0_{cell}=E^0_{cathode}- E^0_{anode}[/tex]

Where both [tex]E^0[/tex] are standard reduction potentials.

[tex]E^0_{[Pb^{2+}/Pb]}= -0.13V[/tex]

[tex]E^0_{[Zn^{2+}/Zn]}=-0.76V[/tex]

[tex]E^0_{cell}=E^0_{[Pb^{2+}/Pb]}- E^0_{[Zn^{2+}/Zn]}[/tex]

[tex]E^0_{cell}=-0.13-(-0.76)=0.63V[/tex]

Thus the [tex]E_{cell}[/tex] is 0.63 V