The pH of a solution is 8.83±0.048.83±0.04 . What is the concentration of H+H+ in the solution and its absolute uncertainty?

Respuesta :

Answer:

The concentration of [tex]H^{+}[/tex] is 1.48  × [tex]10^{-9}[/tex] M

The absolute uncertainty of [tex][{H^{+}][/tex] is ±0.12 × [tex]10^{-9}[/tex] M

The concentration of [tex]H^{+}[/tex] is written as 1.48(±0.12) × [tex]10^{-9}[/tex] M

Explanation:

The pH of a solution is given by the formula below

pH = [tex]-log_{10}[{H^{+}][/tex]

∴ [tex][H^{+}] = 10^{-pH}[/tex]

where [tex][{H^{+}][/tex] is the [tex]H^{+}[/tex] concentration

From the question,

pH = 8.83±0.04

That is,

pH =8.83 and the uncertainty is ±0.04

First, we will determine [tex][{H^{+}][/tex] from

[tex][H^{+}] = 10^{-pH}[/tex]

[tex][{H^{+}] = 10^{-8.83}[/tex]

[tex][{H^{+}] = 1.4791[/tex] × [tex]10^{-9}[/tex] M

[tex][{H^{+}] = 1.48[/tex] × [tex]10^{-9}[/tex] M

The concentration of [tex]H^{+}[/tex] is 1.48  × [tex]10^{-9}[/tex] M

The uncertainty of [tex][{H^{+}][/tex]  ( [tex]U_{[H^{+}] }[/tex] ) from the equation [tex][H^{+}] = 10^{-pH}[/tex] is

[tex]U_{[H^{+}] } = 2.303 \\[/tex] × [tex]{[H^{+}] }[/tex] × [tex]U_{pH }[/tex]

Where [tex]U_{[H^{+}] }[/tex] is the uncertainty of [tex][{H^{+}][/tex]

[tex]U_{pH }[/tex] is the uncertainty of the pH

Hence,

[tex]U_{[H^{+}] }[/tex] = 2.303 × 1.4791 × [tex]10^{-9}[/tex] × 0.04

[tex]U_{[H^{+}] }[/tex] = 1.36 × [tex]10^{-10}[/tex] M

[tex]U_{[H^{+}] }[/tex] = 0.12 × [tex]10^{-9}[/tex] M

Hence, the absolute uncertainty of [tex][{H^{+}][/tex] is ±0.12 × [tex]10^{-9}[/tex] M