0.73 grams of toluene was reacted with 2.0 grams of potassium permanganate in presence of 7.0 mL of 6 Molar potassium hydroxide and 30 mL of water. After refluxing for 1 hour the reaction mixture was treated with 6 Molar sulfuric acid to pH~ 2.0 followed by oxalic acid. On cooling this solution in an ice bath 0.633 grams of pure benzoic acid was obtained. Calculate the % yield of benzoic acid in this reaction.

Respuesta :

Answer:

The value is [tex]k =66\%[/tex]

Explanation:

From the question we are told that

The mass of toluene [tex] m_t =0.73 \ g [/tex]

The mass of potassium permanganate is [tex] m =2.0 \ g [/tex]

The volume of potassium hydroxide V = 7.0 mL

The concentration of potassium hydroxide C = 6 M

The mass of benzoic acid is [tex]m_b = 0.633 \ g[/tex]

Generally the % yield of benzoic acid is mathematically represented as

[tex]k = \frac{m_b}{Z} * 100[/tex]

Here Z is the theoretical yield which is mathematically represented as

[tex]Z = \frac{E}{W} * m_t [/tex]

Here W is the molecular weight of product (benzoic acid) with value  

       W  = 92.14 \ g

E is the molecular weight of reactant (toluene)with a constant value  of  

    E =  122.12 g

So

     [tex]Z =  \frac{122.12 }{92.14}  *  0.73 [/tex]

=>    [tex]Z = 0.968 \  g  [/tex]

So

     [tex]k  =  \frac{0.633}{0.968}  * 100[/tex]

=>   [tex]k  =66\%[/tex]