12.5 mL of 0.280 M HNO3 and 5.0 mL of 0.920 M KOH are mixed. Is the resulting solution acidic, basic or neutral?

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Answer:

The resulting solution is basic.

Explanation:

The reaction that takes place is:

  • HNO₃ + KOH → KNO₃ + H₂O

First we calculate the added moles of HNO₃ and KOH:

  • HNO₃ ⇒ 12.5 mL * 0.280 M = 3.5 mmol HNO₃
  • KOH ⇒ 5.0 mL * 0.920 M = 4.6 mmol KOH

As there are more KOH moles than HNO₃, the resulting solution is basic.

The resulting solution is basic.

• It is known that KOH is a base and HNO3 is an acid, so when they mix they undergo a neutralization reaction.  

• The reaction between there will be,  

HNO3 + KOH ⇔ KNO3 + H2O

Based on the given information,

• The volume of HNO3 is 12.5 ml and the molarity is 0.280 M, and the volume of KOH is 5 ml and the molarity is 0.920 M.

Now 1 mole of HNO3 completely reacts with 1 mole of KOH,

The millimoles of HNO3 is,

[tex]= Molarity * Volume (in ml)\\= 0.280 * 12.5\\= 3.5 mmol[/tex]

The millimoles of KOH is,

[tex]= Molarity * Volume (in ml)\\= 0.920 * 5.0\\= 4.6 mmol[/tex]

Now it can be seen that 3.5 millimoles of HNO3 completely reacts with 3.5 millimoles of KOH. Now we are left with 4.6-3.5 = 1.1 mmol of KOH.

Thus, KOH is in excess amount present in the solution, and as it is basic in nature, therefore, the resultant solution would be basic in nature.

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