Answer: The initial volume of the gas is 7.72 L
Explanation:
For an isothermal process the temperature is constant.
[tex]PV=nRT[/tex]
as P = pressure = 1 atm ,
V = Volume = 25 L
n = moles
R= gas constant
T = temperature
[tex]PV=1atm\times 25L[/tex]
[tex]nRT=25Latm=25\times 101.3J=2532.5J[/tex] (1Latm=101.3 J)
For isothermal reaction :
[tex]w=-2.303nRT\log\frac{V_2}{V_1}[/tex]
where , w = work done by system = -ve
n = moles = 1
[tex]V_2[/tex] = final volume = 25 L
[tex]V_1[/tex] = initial volume = ?
[tex]-3000J=-2.303\times 2532.5\log \frac{25}{V_1}[/tex]
[tex]V_1=7.72L[/tex]
Thus initial volume of the gas is 7.72 L