Answer:
Nathan Zimmer lives in Northeastern Pennsylvania which is an area with elevated methane gas levels in the drinking water. It is not toxic but highly explosive, however, a high concentration of methane gas level can lead to Asphyxiation. It is a condition that can cause death, in this person can not get enough amount of oxygen to lungs.
Sandi Smith lives in rural western Nebraska spends a long time on a wheat farm who can get allergic reactions due to dust from moldy hay, straw and grain. Pesticides and herbicides can result in chemical burns, respiratory illness, or poisoning.