The element in period 6 that would have chemical properties similar to nitrogen is bismuth.
The chemical properties of an element like oxidation states, reactivities, among others, are mainly related to its electronic configuration.
Elements located in the same group on the periodic table will have similar chemical properties since the electron configuration in their outer shell is the same.
The electronic configuration of nitrogen is the following:
1s² 2s² 2p³
Of all the elements of period 6, bismuth is the one that is located in the same nitrogen group (group 15), whose electronic configuration is:
[Xe] 4f¹⁴ 5d¹⁰ 6s² 6p³
The electron configuration of group 15 (ns² np³) is which gives them chemical properties like high reactivity at high temperatures, high reactivity with oxidant acids (except for nitrogen), low or almost no reactivity with water, etc.
Therefore, bismuth is the element in period 6 that would have chemical properties similar to nitrogen.
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