The equilibrium constant, Kp, for the following reaction is 0.636 at 600K.

COCl2(g) <=> CO(g) + Cl2(g)

If an equilibrium mixture of the three gases in a 16.9 L container at 600K contains COCl2 at a pressure of 0.836 atm and CO at a pressure of 0.551 atm, the equilibrium partial pressure of Cl2 is ............ atm.

Respuesta :

Answer: The equilibrium partial pressure of [tex]Cl_{2}[/tex] is 0.964 atm.

Explanation:

Given: [tex]K_{p} = 0.636[/tex]

[tex]P_{COCl_{2}} = 0.836 atm[/tex]

[tex]P_{CO} = 0.551 atm[/tex]

The given reaction equation is as follows.

[tex]COCl_{2}(g) \rightleftharpoons CO(g) + Cl_{2}(g)[/tex]

Formula used to calculate the partial pressure of [tex]Cl_{2}[/tex] is as follows.

[tex]K_{p} = \frac{P_{CO} \times P_{Cl_{2}}}{P_{COCl_{2}}}[/tex]

Substitute the values into above formula as follows.

[tex]K_{p} = \frac{P_{CO} \times P_{Cl_{2}}}{P_{COCl_{2}}}\\0.636 = \frac{0.551 atm \times P_{Cl_{2}}}{0.836 atm}\\P_{Cl_{2}} = 0.964 atm[/tex]

Thus, we can conclude that the equilibrium partial pressure of [tex]Cl_{2}[/tex] is 0.964 atm.