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Which of the following alcohols will give a positive chromic acid test?
(A) tert-butanol (B) cyclohexanol (C) pentan-3-ol
(D) both A and B (E) both B and C

Respuesta :

the answer is both B and C

positive chromic acid test is indicated by disappearance of orange colour from chromic ions and appearance of blue-green color from Chromium (iii) ion (reduction of chromium ion from CrO4 - to Cr3+)

positive chromic test indicated functional groups that can be oxidized.

cyclohexanol can be oxidized to become cyclohexanone

and pentan-3-ol can be oxidized to become pentan-3-one

hence both B and C will show positive chromic acid test

A) tert butanol although contains alcohol functional group, cannot be further oxidized as it is a tertiary alcohol

(E) Both B and C

What is chromic acid test?

  • The chromic acid test uses the Jones reactant to oxidize aldehydes and alcohols and reduce the chromic acid, resulting in a color change.
  • Positive chromic acid test is indicated by disappearance of orange color from chromic ions and appearance of blue-green color from Chromium (III) ion (reduction of chromium ion from [tex]CrO_4^- \text{to } Cr^{3+}[/tex])

Positive chromic test indicated functional groups that can be oxidized.

⇒Cyclohexanol can be oxidized to become cyclohexanone.

⇒Pentan-3-ol can be oxidized to become pentan-3-one.

Hence, both B and C will show positive chromic acid test.

A) tert-butanol although contains alcohol functional group, cannot be further oxidized as it is a tertiary alcohol.

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