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Electronegativity measures how much an atom likes to pull electrons away from another one. Ionization energy measures how much an atom doesn't want to lose electrons. As an atom that wants to gain electrons will clearly not want to lose electrons, these trends are basically identical.
Taking into account the definition of ionization energy and electronegativity, you can say that the significance of the similarity of these trends is that while electrons are more attracted to the nucleus (electronegativity), more energy is needed to extract an electron from a neutral atom (ionization energy).
Ionization energy
Electrons are held in atoms by their attraction to the nucleus, which means that energy is needed to remove an electron from the atom.
Ionization energy, also called ionization potential, is the necessary energy that must be supplied to a neutral, gaseous, ground-state atom to remove an electron from an atom. When an electron is removed from a neutral atom, a cation with a charge equal to +1 is formed.
The further away the electron is from the nucleus, the easier it is to remove it, that is, the less energy is needed.
In a group the atoms have the same electronic structure in the outermost shell. But when going down in the same group, the electrons find themselves in shells that are farther and farther away from the nucleus, being less and less attracted. The size of the atom increases as the number of electronic shells increases, increasing the atomic radius when descending in a group. But the electrons are farther from the nucleus, and the easier it will be to expel them. That is, its extraction from the atom is facilitated. So the ionization energy decreases when descending in a group. In other words, ionization energy is a function of atomic radius; the larger the radius, the less energy is required to remove the electron from the outermost orbital.
By increasing the atomic number of the elements of the same period, the nuclear attraction on the outermost electron increases, since the atomic radius decreases and the effective nuclear charge on it increases.
For this reason, in a period, as the atomic number increases, the ionization energy becomes greater.
Electronegativity
The electronegativity of an element is defined as the relative ability of an atom to attract electrons from another atom to chemically bond and form a compound.
In other words, electronegativity is a measure of the attractive force that one atom exerts on the electrons of another when a chemical bond forms.
In the groups, the electronegativity decreases from top to bottom because the valence shell moves away from the nucleus and with this the attraction that the nucleus exerts on the valence electrons decreases.
In the periods, the electronegativity increases from left to right, because the number of electrons in the valence shell increases, so the attraction of other electrons increases to complete the valence shell and reach a stable state.
Similarityof the trends
The significance of the similarity of these trends is that while electrons are more attracted to the nucleus (electronegativity), more energy is needed to extract an electron from a neutral atom (ionization energy).
Then, electronegativity is related to ionization energy in the following way: an atom with a high ionization potential has a high electronegativity. On the contrary, atoms with low ionization potential have small electronegativity.
Learn more about
- electronegativity:
- brainly.com/question/14481608?referrer=searchResults
- brainly.com/question/21298480?referrer=searchResults
- ionization energy:
- brainly.com/question/16243729?referrer=searchResults
- brainly.com/question/11623163?referrer=searchResults
- brainly.com/question/1602374?referrer=searchResults
