Calculate the second ionization energy of the metal M (?Hion2� in kJ/mol) using the following data:


Lattice enthalpy of MO(s), ?Hl� = -2383 kJ/mol

Bond dissociation enthalpy of O2(g) = +498 kJ/mol

First electron affinity of O = -141 kJ/mol

Second electron affinity of O = +744 kJ/mol

Enthalpy of sublimation of M = + 130 kJ/mol

First ionization energy of M = + 267 kJ/mol

Standard enthalpy of formation of MO(s), ?Hf� = -307 kJ/mol

Respuesta :

From the information provided in the question, the second ionization energy of the metal is  578 kJ/mol.

From the question, we have the following information;

Lattice enthalpy of MO(s) = -2383 kJ/mol

Bond dissociation enthalpy of O2(g) = +498 kJ/mol

First electron affinity of O = -141 kJ/mol

Second electron affinity of O = +744 kJ/mol

First ionization energy of M = + 267 kJ/mol

Heat of sublimation of M = + 130 kJ/mol

Standard enthalpy of formation of MO(s) = -307 kJ/mol

Using Hess law of constant heat summation;

ΔHf = ΔHs + BE + ∑IE + ∑EA + U

ΔHs  = Heat of sublimation of metal

ΔHf = Heat of formation MO

BE = Bond energy of O2

∑EA  = sum of electron affinities of Oxygen

∑IE  = Sum of the ionization energies of M

U = Lattice energy of MO

Let the second ionization energy be x

Substituting values;

(-307) = 130 + 498 + (267 + x) + 603 + (-2383)

(-307) = -885 + x

-x =   -885 + 307

-x = -578

x = 578 kJ/mol

The second ionization energy of the metal is  578 kJ/mol.

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