You wish to prepare a buffer containing CH3COOH with a pH of 5.14. If the pka of acetic acid is 4.74, what ratio of
[CH3COO-]/[CH3COOH] must you use?
A 0.70
B 4.0
C 0.40
D 2.0
E 2.5

Respuesta :

Answer:

E

Explanation:

Recall the Henderson-Hasselbalch equation:

[tex]\displaystyle \text{pH} = \text{p}K_a + \log \frac{[\text{Base}]}{[\text{Acid}]}[/tex]

For a pH of 5.14 with the given pKa of 4.74, solve for the ratio between acetate and acetic acid:

[tex]\displaystyle \begin{aligned} (5.14) & = (4.74) + \log\frac{[\text{CH$_3$COO$^-$}]}{[\text{CH$_3$COOH}]} \\ \\ \log\frac{[\text{CH$_3$COO$^-$}]}{[\text{CH$_3$COOH}]}& = 0.40 \\ \\ \frac{[\text{CH$_3$COO$^-$}]}{[\text{CH$_3$COOH}]} & = 10^{0.40} \\ \\ & = 2.5\end{aligned}[/tex]

In conclusion, the answer is E.