The scientist that performed the cathode ray experiment leading to the discovery of electrons is J.J. Thomson.
A cathode ray is a tube that contains negatively charged electrode( that is the cathode) which emits electrons when heated at a low pressure.
The cathode ray was used by the scientist, J.J. Thomson to find the ratio of charge to mass (e/m) of the electrons.
Therefore, the scientist that performed the cathode ray experiment leading to the discovery of electrons is J.J. Thomson.
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