The second reaction with the volume of 5L will occur faster as compared to the first reaction of volume 10L.
Volume is inversely proportional to the rate of reaction.
As volume increases rate of reaction decreases and as volume decreases rate of reaction increases.
Let's consider a reaction A  →  B.
r is rate of reaction and K is rate constant, A is the concentration of reaction.
r = k(A)
r is directly proportional to the A.
But the concentration of A is in Moles/liters (i.e. moles per unit volume)
r is inversely proportional to the volume of vessel or chamber.
 Hence as volume increases rate of reaction decreases.
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