Since benzene is a covalently bonded chemical, ions and ionic bonds have no bearing on it. Simply put, boiling will cause the molecules to split from one another and turn into a gas.
Benzene boils at a greater temperature than other hydrocarbons with comparable molecular sizes, at 80°C (pentane and hexane, for example). The increased boiling point is most likely caused by how simple it is to create transient dipoles involving the delocalized electrons. At 111°C, methylbenzene begins to boil. Pure benzene and pure toluene have normal boiling points of 80.1 C and 110.6 C, respectively. Due to fewer intermolecular interactions, benzene has a lower boiling point than toluene.
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