The ideal gas law states that the relationship between partial pressure and volume is inverse. Additionally, it relates temperature and moles in a direct proportion. The partial pressures of the gases are discovered to be at equilibrium in the following process at room temperature and to be PN2 = 0.094 atm, PH2 = 0.039 atm, and PNH3 = 0.003 atm.
Each reactant's equilibrium partial pressure will be equal to its stated initial partial pressure minus x. For reactions that have the first general form below or the second form, the equilibrium partial pressure of product will be x or 2x.
The equilibrium partial pressures (in the bar) of CO, H2O, CO2, and H2 are 4−p,4−p, and respectively.
Let p bar be the equilibrium partial pressure of hydrogen.
The expression for the equilibrium constant is
Kp=PCOPH2OPCO2PH2=(4−p)(4−p)p×p=0.1
p=1.264−0.316p
p=0.96 bar.
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