A 35.00-mL solution of 0.2500 M HF is titrated with a standardized 0.1532 M solution of NaOH at 25°C.(e) What is the pH at 0.50 mL after the equivalence point?

Respuesta :

The pH at 0.50 mL after the equivalence point is 11.14

Total V = 57.11 mL + 0.5 mL = 57.61 mL = 0.05761 L

nNaOH aggregate = 0.1532 mol / L * 0.05761 L = 8.83x10 ^ -3 moles

nHF = 8.75 x10 ^ -3 moles

nNaOH final = 8.83x10 ^ -3 moles - 8.75 x10 ^ -3 moles = 8x10 ^ -5 moles

[NaOH] final = [OH-] = 8x10 ^ -5 moles / 0.05761 L = 1.39x10 ^ -3 M

pOH = - Log (1.39x10 ^ -3) = 2.86

pH = 14 - 2.86 = 11.14.

Hence, pH at 0.50 mL after the equivalence point is 11.14

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