{Ag^+] is 2.759 M.
Given ,
Calomel: Hg2Cl2 + 2e^- ==> 2Hg(l) + 2Cl^- (aq) Ā , Ā E^0 = 0.24V
Silver : Ā Ag^+ (aq) + e^- ==> Ag(s) Ā , Ā E^0 = 0.80 V
Ecell = 0.060V
We know , E^0 cell =( 0.80-0.24)V =0.56 V
According the Nernst equation ,
Ecell = E^0cell - 0.0592/2 log [product/reactant ]
Ecell = Ā E^0cell - 0.0592/2 log {[Ag^+]2/[Cl^-]2}
0.060 = 0.56 - 0.0592/2log{[Ag^+]2/[1]}
0.5 = 0.0592/2 ( 2 log[Ag^+] )
0.5/0.0592= log [Ag^+]
taking antilog on both sides ,
[Ag^+] =2.759 M
Hence , [Ag^+] is 2.759 M .
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