Ba(ClO2)2 and H2SO4 Â are need to prepare Chlorous acid.
What is Chlorous acid?
Chlorous acid is an inorganic compound with the formula HClO2. It is a weak acid. Chlorine has oxidation state +3 in this acid. The pure substance is unstable, disproportionating to hypochlorous acid (Cl oxidation state +1) and chloric acid (Cl oxidation state +5):
2 HClO2 → HClO + HClO3
Although the acid is difficult to obtain in pure substance, the conjugate base, chlorite, derived from this acid is stable. One example of a salt of this anion is the well-known sodium chlorite. This and related salts are sometimes used in the production of chlorine dioxide.
Chlorous acid can be obtained by reacting barium or lead chlorite with dilute sulfuric acid.
Ba(ClO2)2 + H2SO4 → BaSO4 + 2 HClO2
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