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A clear cloudless day-time sky is blue because molecules in the air scatter blue light from the sun more than they scatter red light. When we look towards the sun at sunset, we see red and orange colours because the blue light has been scattered out and away from the line of sight.
Hope this helps;)
When sunlight reaches Earth's atmosphere, it is scattered in all directions by all the gases and particles in the air. Blue is scattered by air molecules more than other colors because it travels as shorter, smaller waves. This is why we see a blue sky most of the time.