1NaHCO3 + 1HC2H3O2 → 1Na(C2H3O2) + 1H2CO3
First reaction is balanced, there is no need to write coefficient 1 in front of molecule.
1H2CO3 → 1H2O + 1CO2
Second reaction is also balanced. This type of reaction is calling chemical decomposition or analysis, because one molecule separats into its two simpler compounds.