Hello!
After the addition of a small amount of acid, a reasonable value of buffer pH would be 5,15.
If initially there are equal amounts of a weak acid and its conjugate base, the pH would be equal to the pKa, according to the Henderson-Hasselbach equation:
[tex]pH=pKa+log( \frac{[A^{-}] }{[HA]} ) \\ \\ if [A^{-}]=[HA] \\ \\ pH=pKa + log (1) \\ \\ pH=pKa + 0=5,25[/tex]
So, when adding a little amount of acid the pH should be only a little lower than the pKa. The value from the list that is a little lower than the pKa is 5.15
Have a nice day!