According to Graham's Law of Diffusion," Diffusion of Gas is inversely proportional to square root of its Molecular Mass or Density".
rᵇ/rᵃ = [tex] \sqrt{da/db} [/tex]
Or,
rᵇ/rᵃ = [tex] \sqrt{Ma/Mb} [/tex] ----- (1)
As,
Ma = 275 g/mol
Mb = 205 g/mol
Putting Values in eq.1,
rᵇ/rᵃ = [tex] \sqrt{275/205} [/tex]
rᵇ/rᵃ = 1.15
Result:
Perfume B will diffuse 1.15 times faster than Perfume A. Hence, Perfume B will be first smelled by the person.