Mark the false statements.
a. a π bond restricts rotation about the bond axis.
b. bonds formed from the overlap of atomic s orbitals are always σ bonds.
c. a triple bond consists of one π bond and two σ bonds.
d. end-to-end overlap of orbitals results in a bond with electron density above and below the bond axis.
e. a π bond consists of two pairs of electrons. f. two σ bonds comprise a double bond.

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Answer:

c. a triple bond consists of one π bond and two σ bonds.

d. end-to-end overlap of orbitals results in a bond with electron density above and below the bond axis.

e. a π bond consists of two pairs of electrons.

f. two σ bonds comprise a double bond.

Explanation:

Mark the false statements.

a. a π bond restricts rotation about the bond axis. TRUE.

b. bonds formed from the overlap of atomic s orbitals are always σ bonds. TRUE.

c. a triple bond consists of one π bond and two σ bonds. FALSE. A triple bond consists of one σ bond and two π bonds.

d. end-to-end overlap of orbitals results in a bond with electron density above and below the bond axis.  FALSE. End-to-end overlap of orbitals results in a bond with electron density along the bond axis.

e. a π bond consists of two pairs of electrons. FALSE. A π bond consists of one pair of electrons.

f. two σ bonds comprise a double bond. FALSE. A double bond is comprised of one σ bond and one π bond.

A bond is formed when atomic orbitals overlap with each other.

A bond is formed by the overlap of orbitals. A sigma bond is formed by end  to end overlap of atomic orbitals while a pi bond is formed by side by side overlap of atomic orbitals. In a pi bond, the electron density is located above and below the bond axis of the bond while in a sigma bond, electron density is located along the axis of the bond.

The following are false statements;

  • a triple bond consists of one π bond and two σ bonds.
  • two σ bonds comprise a double bond.
  • end-to-end overlap of orbitals results in a bond with electron density above and below the bond axis.
  • a π bond consists of two pairs of electrons.

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