In a first-order decomposition reaction. 36.8% of a compound decomposes in 7.6 min. How long (in min) does it take for 88.8% of the compound to decompose?

Respuesta :

Answer: 36.5 minutes

Explanation:

Expression for rate law for first order kinetics is given by:

[tex]t=\frac{2.303}{k}\log\frac{a}{a-x}[/tex]

where,

k = rate constant  

t = age of sample

a = let initial amount of the reactant  = 100

a - x = amount left after decay process  

a) for completion of 36.8 % of reaction  

[tex]7.6=\frac{2.303}{k}\log\frac{100}{100-36.8}[/tex]

[tex]k=\frac{2.303}{7.6}\times 0.19[/tex]

[tex]k=0.060min^{-1}[/tex]

b) for completion of 88.8 % of reaction  

[tex]t=\frac{2.303}{k}\log\frac{100}{100-88.8}[/tex]

[tex]t=\frac{2.303}{0.060}\log\frac{100}{11.2}[/tex]

[tex]t=\frac{2.303}{0.060}\times 0.95[/tex]

[tex]t=36.5min[/tex]

It will take 36.5 minutes for 88.8% of the compound to decompose.