Mole itself is the number of particles contained in a substance
1 mole = 6.02.10²³ particles
Mole : the ratio of the amount of substance mass and its molar mass
[tex]\large{\boxed{\boxed{\bold{mole=\frac{mass}{molar\:mass}}}}[/tex]
Molarity is a way to express the concentration of the solution
Molarity shows the number of moles of solute in every 1 liter of solute or mmol in each ml of solution
[tex]\large{\boxed {\bold {M ~ = ~ \frac {n} {V}}}[/tex]
Molar concentration of methanol=24.7 M
Volume of solution = 500 ml = 0.5 L
[tex]\tt mol=M\times V\\\\mol=24.7\times 0.5\\\\mol=12.35[/tex]