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HCl has a lower vapor pressure at a given temperature.

What is vapor pressure?

  • Vapor pressure (or vapor pressure in English-speaking countries other than the United States; see spelling differences) is defined as the pressure exerted by a vapor in thermodynamic equilibrium with its condensed phases (solid or liquid) in a closed system at a given temperature.
  • The equilibrium vapor pressure indicates the rate of evaporation of a liquid.
  • It refers to the proclivity of particles to escape from a liquid (or a solid).
  • A volatile substance is one that has a high vapor pressure at normal temperatures.
  • The pressure exerted by vapor above a liquid surface is referred to as vapor pressure.

To find which has a lower vapor pressure, HF or HCI:

  • While HF can form hydrogen bonds with water, HCI will completely dissociate into more charged ions that will interact with water molecules via stronger ion-dipole forces.
  • As a result, HCl has a lower vapor pressure.

Therefore, HCl has a lower vapor pressure at a given temperature.

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