First step is to balance the chemical equation:
Sn(s) + 4HF(g) → SnF2(s) + 2H2(g)
To find the mass in grams of hydrogen fluoride needed to react with 5 moles of tin:
1. Calculate the molar mass of HF:
 Molar mass of H = 1g/mol
 Molar mass of F = 19g/mol
 Molar mass of HF = 1g/mol + 19g/mol = 20g/mol
2. Calculate the number of moles of HF needed using the balanced equation:
 5 moles of Sn × (4 moles of HF / 1 mole of Sn) = 20 moles of HF
3. Convert moles to grams:
 Mass = moles × molar mass
 Mass = 20 moles × 20g/mol = 400g
So, 400 grams of hydrogen fluoride are needed to react with 5 moles of tin.