The ¹H-NMR of 1-Bromobutane is shown below,
There are Four signals found in the proton NMR spectrum of 1-Bromobutane.
Triplet Signal at ≈ 3.40 ppm (Down Field = Deshielded) is for methylene group directly attached to Bromine atom.
Multiplet Signal at ≈ 1.8 ppm is for methylene which is present between two methylene groups. The shielding effect is increasing as moving away from Bromine atom.
Multiplet Signal at ≈ 1.49 ppm is for methylene which is present between terminal methyl and methylene groups. The shielding effect is increasing as moving away from Bromine atom.
Triplet Signal at ≈ 0.9 ppm (Up Field = Most Shielded) is for terminal methyl group attached to methylene group.
Result:
Four Signals are found in the ¹H-NMR of 1-Bromobutane.